Product ID:G-33 GLYCERIN
MSDS Date:02/01/1989
FSC:6810
NIIN:00-222-2636
MSDS Number: BDJXZ

Emergency Phone: 201-796-7100/201-796-7523

Info Phone: 201-796-7100/800-424-9300(CHEMTREC)

Cage: 1B464

Telephone: 201-796-7100

Cage: 1B464

GLYCERIN

CAS: 56-81-5

RTECS: MA8050000

Fraction By Weight: 99.9%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 (MIST) 9293

LD50 LC50 Mixture:LD50 ORAL RAT IS 12600 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IN CASE OF EYE AND SKIN
CONTACT, IRRITATION, SKIN DEHYDRATION. NOT CONSIDERED AN INHALATION
HAZARD. IF INGESTED, MAY CAUSE DIGESTIVE TRACT IRRITATION, MAY
AFFECT CENTRAL NERVOUS SYSTEM AND KIDN EYS. CHRONIC: REPEATED OR
PROLONGED CONTACT MAY CAUSE DERMATITIS.
Explanation of Carcinogenicity:NONE OF THE INGREDIENTS IN THIS PRODUCT
IS LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES: STRONG STINGING AND BURNING. SKIN: MILD
IRRITATION AND REDNESS. INHALATION: MUCOUS MEMBRANE IRRITATION.
INGESTION: HEADACHE, NAUSEA, VOMITING, MAY ALSO INCLUDE DIGESTIVE
IRRITATION, INSOMNIA, DI ZZINESS, DIARRHEA, FEVER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF
IRRITATION PERSISTS, SEE DOCTOR. SKIN: WASH WITH MILD SOAP AND
WATER WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. SEE DOCTOR.
INHALATION : REMOVE VICTIM TO FRESH AIR. GIVE OXYGEN/CPR IF NEEDED.
SEE DOCTOR. INGESTION: INDUCE VOMITING. GIVE OXYGEN/CPR IF NEEDED.
SEE DOCTOR. GASTRIC LAVAGE SHOULD BE PERFORMED BY MEDICAL
PERSONNEL.

Flash Point Method:CC
Flash Point:=160.C, 320.F
Autoignition Temp:=370.C, 698.F
Lower Limits:0.9
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, ALCOHOL FOAM, HALON
OR DRY CHEMICAL. WATER OR FOAM MAY CAUSE FROTHING.
Fire Fighting Procedures:WEAR PROTECTIVE EQUIPMENT AND SCBA.KEEP
UPWIND.MOVE CONTAINER FROM FIRE AREA IF POSSIBLE.DO NOT USE WATER
STREAM.COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.

Spill Release Procedures:REMOVE PERSONNEL. ELIMINATE IGNITION SOURCES.
VENTILATE AREA. WEAR PROTECTIVE CLOTHING AND EQUIPMENT. ABSORB IN
INERT MATERIAL AND PLACE IN APPROPRIATE DISPOSAL CONTAINER AND
COVER. FLUSH AREA WITH LA RGE AMOUNTS OF WATER.

Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED
AREA. PROTECT FROM PHYSICAL DAMAGE, HEAT, IGNITION SOURCES AND
INCOMPATIBLE MATERIALS. KEEP CONTAINERS CLOSED.
Other Precautions:AVOID EYE AND SKIN CONTACT. DO NOT BREATHE VAPORS.

Respiratory Protection:NONE NORMALLY REQUIRED. NIOSH/MSHA-APPROVED
RESPIRATOR OR SCBA AS APPROPIATE FOR EXPOSURE OF CONCERN.
Ventilation:MECHANICAL (GENERAL) VENTILATION TO KEEP EXPOSURE LEVELS
BELOW PEL.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE
EXPOSURE FROM PROLONGED OR REPEATED CONTACT. EYE BATH AND SAFETY
SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NONE.

HCC:V5
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=290.C, 554.F
Melt/Freeze Pt:=20.C, 68.F
Vapor Pres:<0.01@122F
Vapor Density:3.1
Spec Gravity:1.2613
pH:7
Solubility in Water:COMPLETE
Appearance and Odor:ODORLESS,COLORLESS TO PALE YELLOW, HYGROSCOPIC,
SYRUPY LIQUID, WARM, SWEET TAST
Percent Volatiles by Volume:NIL

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, INORGANIC ACIDS, SODIUM HYDRIDE, LEAD OXIDE.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:ACROLEIN, CARBON MONOXIDE, CARBON
DIOXIDE, INCOMPLETELY BURNED CARBON PRODUCTS.

Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.